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Faves.
Sam
Carol

Yes.
Bruce
Thor
Valkyrie

Needs prior CR.
Pepper
Maria

Friends/family for life.
Yelena
Peter
Fury
Rhodey
Laura
Etc.
While Nat is taken between Infinity War and Endgame, I'll happily play around canon points to best fit the scenario. And while Nat is taken from the MCU, I am more than happy to incorporate some comics into the mix, if that's your jam. Otherwise I'm fine with keeping everything strictly to the MCU.
Mun has seen Black Widow.